If you find it hard to cut out an image on photoshop, here's your guide.
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1. Open the image you want to work with.
2. Right click on the Lasoo Tool, and select Magnetic Lasoo Tool.
3. Go around your Toon/Picture with the Magnetic Lasoo Tool, try to make sure it is near the Toon outline.
4. Make sure it goes around the whole of the Toon, and when you get to the end Double click.
5. Then CTRL+X to cut the image.
6. Open the background you want to put the picture on, then CTRL+V
7. Use the Magic Wand Tool to get rid of any thing that shouldnt be there.
8. Press CRTL+D to deselect the selectioned part of the image.
9. Use the rubber to get rid of any exess colour on the outline.

Tah Dah!
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Its not much of a clean cut, but if you take time to do it, it will be more clean.
More tutorial's coming soon!